bromotris (triphenylphosphine) rhodium (I) CAS:14973-89-8

Katswiri weWilkinson unoshandiswa mukuchinja kwakasiyana-siyana kwemakemikari, kusanganisira hydrogenation, hydrosilylation, uye hydroformylation reactions. Unoshandiswawo mukugadzira makemikari akanaka, mishonga, nezvinhu zvepamusoro. Kugona kwekatswiri uyu kuita kuti maitiro ekusarudza uye anoshanda ekugadzirisa zvinhu ashande zvakanaka kwakaita kuti ive chishandiso chakakosha mukugadzira nzira itsva dzekugadzira uye kugadzira zvigadzirwa zvemakemikari zvinokosha.

Imwe yenzira dzakakosha dzekushandisa Wilkinson's catalyst ndeyekugadzira linear aldehydes kuburikidza ne hydroformylation reaction. Catalyst iyi inokurudzira kuwedzera carbon monoxide ne hydrogen mu olefin, zvichikonzera kuumbwa kwe aldehyde. Iyi nzira inoshandiswa zvakanyanya mukugadzira ma plasticizers, sipo, nemamwe makemikari akakosha emuindasitiri.

Chinhu chinobatsira Wilkinson chinoshandiswawo mukugadzira zvigadzirwa zvechisikigo zvakaoma uye mishonga. Hunhu hwayo hwakasiyana uye reactivity inoita kuti ive chishandiso chakakosha mukusimudzira shanduko dzakasiyana-siyana dzemakemikari. Pamusoro pezvo, inoshandiswa mukugadzira makemikari akakosha, akadai se chiral ligands, nezvinhu zvepamusoro, zvakaita se conductive polymers.

Kazhinji, Bromotris (triphenylphosphine) rhodium (I) kana Wilkinson's catalyst imusanganiswa unoshanda zvakasiyana-siyana une mashandisirwo akakosha mukugadzirwa kwezvinhu zvakasikwa, sainzi yezvinhu, uye maitiro emakemikari emaindasitiri. Kushandiswa kwayo kunowedzera mukugadzirwa kwemabhatiri anoshanda zvakanyanya uye maseru emafuta, uko kugadzikana uye kushanda pakupisa kwakanyanya kwakakosha. Kukosha kwemusanganiswa uyu mumunda wemakemikari eorganic uye kugadzirwa kwemakemikari emaindasitiri hakugone kupfuudzwa zvakanyanya.