carbanide, chloropalladium(1+),(1Z,5Z)-cycloocta-1,5-diene CAS:63936-85-6

Iyo Palladium(II) Chloro complex [(C8H12)(Cl)Pd] inoumbwa nekubatana pakati pePdCl4 uye trans-(1R,5S)-cycloocta-1,5-diene molecules kuburikidza ne dative bonds. Chigadzirwa chinobuda chine dienyl ligand imwe chete yakasungirirwa kune imwe neimwe yenzvimbo ina dzesimbi kuburikidza ne eta-coordinate. Iyi complex ine kugadzikana kwakanyanya kwekupisa nekuda kwemasimba akasimba epakati pemamorekuru mukati mechimiro. Kushandiswa kwayo kunonyanya kuitika mu catalytic processes inosanganisira cross coupling reaction. Semuenzaniso, iyi mhando inobatsira C-C bond formation panguva yeSuzuki Coupling Reaction inosanganisira kubatanidza sp2 hybridized carbon atoms pamwe chete uchishandisa boronic acids se nucleophiles. Iyo itsva bond inogadzirwa inowedzera hunhu hwezvinhu zvinoshandiswa mumidziyo yemagetsi zvichiita kuti zvive zvinobudirira. Uyezve, iyi catalyst inowana kushanda muSonogashira coupling reaction uko sp hybridized atoms dzinobatanidzwa pamwe chete uchishandisa terminal alkynes zvichitungamira pakuumbwa kweC-C bond nokudaro ichiumba mapoka matsva anoshanda ane mukana wekushandiswa munzvimbo dzakasiyana-siyana dzinosanganisira kugadzira mishonga uye sainzi yezvinhu.