Chloroaminodiphenylethylpentafluorophenylksulfonyl)amido((p-cymene)ruthenium(II)) CAS:1026995-71-0

Musanganiswa uyu unoshandiswa zvakanyanya sechinhu chinobatsira pakuchinja kwemakemikari, kusanganisira kuumbwa kwebhondi recarbon-carbon, hydrogenation, uye cross-coupling reactions. Maumbirwo awo akasiyana anoabvumira kuti aite kuti zvinhu zvakasiyana-siyana zve organic zvishande, zvichikonzera kuumbwa kwemamorekuru akaomarara ane sarudzo yepamusoro uye kushanda zvakanaka. Uyezve, (Chloroaminodiphenylethylpentafluorophenylksulfonyl)amido((p-cymene)ruthenium(II) yakaratidza mhedzisiro inovimbisa mukusafanana kwemasero, uko inogona kukonzera chirality mumamorekuru anogadzirisa, zvichigonesa kugadzirwa kwemakomputa eenantiopure. Hunhu uhwu hunonyanya kukosha muindasitiri yemishonga, uko mamorekuru eenantiopure akakosha pakugadzirwa kwemishonga. Kushanda nesimba uye reactivity yekomputa kunoita kuti ive chishandiso chakakosha mukemikari yekugadzira. Inogona kubatsira shanduko dzakaoma, dzakadai sekuumbwa kwemabhondi ecarbon-heteroatom uye kushanda kwemasubstrate asina kushanda, zvichiwedzera mikana yekugadzira kune vaongorori. Mukupedzisa, (Chloroaminodiphenylethylpentafluorophenylksulfonyl)amido((p-cymene)ruthenium(II) ikomputa yakaoma ine mashandisirwo akakosha secatalyst mukugadzirwa kweorganic. Kugona kwayo kumutsa masubstrate akasiyana-siyana uye kukurudzira chirality kunoita kuti ive chishandiso chakakosha mukugadzirwa kwemamorekuru akaomarara, kusanganisira makomputa eenantiopure emishonga.